Acta Crystallographica, Section C: Crystal Structure Communications 1988-05-15

Structure of bis(methanol)(meso-tetraphenylporphinato)manganese(III) hexachloroantimonate bis(tetrachloroethane) solvate.

W R Scheidt, W B Pearson, N Gosal

Index: Acta Crystallogr. C 44 ( Pt 5) , 927-9, (1988)

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Abstract

[Mn(C44H30N4)(CH3OH)2] [SbCl6].2C2H2Cl4, Mr = 1401.93, triclinic, P1, a = 11.104 (3), b = 12.086 (6), c = 12.619 (4) A, alpha = 115.33 (3), beta = 104.75 (2), gamma = 91.75 (3) degrees, V = 1461.3 A3, Z = 1, Dm = 1.58, D chi = 1.59 Mg m-3, lambda(Mo K alpha) = 0.71073 A, mu = 1.359 mm-1, F(000) = 698, T = 293 K, R = 0.079 for 4822 unique observed reflections. The manganese ion is coordinated to two methanol oxygens, Mn--O = 2.283 (5) A, and four porphinato nitrogen atoms, average Mn--N = 2.002 (5) A.

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