Organic reaction in water. Part 3: A facile method for reduction of aromatic rings using a raney Ni–Al alloy in dilute aqueous alkaline solution under mild conditions
T Tsukinoki, T Kanda, GB Liu, H Tsuzuki, M Tashiro
Index: Tsukinoki, Takehito; Kanda, Tadashige; Liu, Guo-Bin; Tsuzuki, Hirohisa; Tashiro, Masashi Tetrahedron Letters, 2000 , vol. 41, # 31 p. 5865 - 5868
Full Text: HTML
Citation Number: 21
Abstract
Reduction of aromatic rings such as phenol, naphthalenes, biphenyls, acenaphthene, and acenaphthylene was smoothly performed using a Raney Ni–Al alloy in dilute aqueous alkaline solution without any organic solvents at 90° C under atmospheric pressure, and the corresponding reduced compounds were obtained in high yields.
Related Articles:
[Boger, Dale B.; Mullican, Michael D. Journal of Organic Chemistry, 1984 , vol. 49, # 21 p. 4033 - 4044]
Metal-free oxidation of aromatic carbon-hydrogen bonds through a reverse-rebound mechanism
[Nature, , vol. 499, # 7457 p. 192 - 196]
[Chemistry Letters, , vol. 35, # 7 p. 780 - 781]
[Tetrahedron Letters, , vol. 24, # 45 p. 4939 - 4942]
[Journal of Organic Chemistry, , vol. 49, # 17 p. 3183 - 3195]