Synthesis of Oxazolidin??2??ones and Imidazolidin??2??ones Directly from 1, 3??Diols or 3??Amino Alcohols using Iodobenzene Dichloride and Sodium Azide
…, WC Gao, WK Wang, C Zhang
Index: He, Tian; Gao, Wen-Chao; Wang, Wei-Kun; Zhang, Chi Advanced Synthesis and Catalysis, 2014 , vol. 356, # 5 p. 1113 - 1118
Full Text: HTML
Citation Number: 7
Abstract
Abstract: A general and efficient method for the synthesis of oxazolidin-2-ones and imidazolidin-2-ones directly from 1, 3-diols and 3-amino alcohols has been developed using the same reagent combination of iodobenzene dichloride (PhICl2) and sodium azide (NaN3). Keywords: imidazolidin-2-ones; iodobenzene dichloride; oxazolidin-2-ones; sodium azide
Related Articles:
1, 3-diol synthesis via controlled, radical-mediated C− H functionalization
[Chen, Ke; Richter, Jeremy M.; Baran, Phil S. Journal of the American Chemical Society, 2008 , vol. 130, # 23 p. 7247 - 7249]
[Liu, Hsing-Jang; Luo, Weide Canadian Journal of Chemistry, 1992 , vol. 70, p. 128 - 134]
The Proline??Catalyzed Asymmetric Amination of Branched Aldehydes
[Cronyn et al. Journal of the American Chemical Society, 1955 , vol. 77, p. 3031,3033]
A β-hydroxyethyl carbanion equivalent
[Klos, Andrew M.; Heintzelman, Geoffrey R.; Weinreb, Steven M. Journal of Organic Chemistry, 1997 , vol. 62, # 11 p. 3758 - 3761]
[Satoh, Tsuyoshi; Yasoshima, Tsukasa; Momochi, Hitoshi Tetrahedron Letters, 2012 , vol. 53, # 16 p. 2074 - 2077]