Journal of the American Chemical Society
2006-09-13
A metal-organic framework with entatic metal centers exhibiting high gas adsorption affinity.
Shengqian Ma, Hong-Cai Zhou
Index: J. Am. Chem. Soc. 128 , 11734, (2006)
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Abstract
A metal-organic framework, PCN-9, containing entatic metal centers, has been synthesized and crystallographically characterized. The H2 and CH4 adsorption enthalpies of PCN-9 are among the highest reported thus far.
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