Chemical Communications 2002-04-21

Tandem intermolecular Suzuki coupling/intramolecular vinyl triflate-arene coupling.

Michael C Willis, Christelle K Claverie, Mary F Mahon

Index: Chem. Commun. (Camb.) (8) , 832-3, (2002)

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Abstract

Treatment of a benzyl substituted meso-ditriflate with boronic acids in the presence of palladium acetate, triphenylphosphine and caesium fluoride results in intermolecular Suzuki coupling followed by vinyl triflate-arene cyclisation to provide, in high yields, single regioisomers of tricyclic-carbocycles.

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