Azolyl substituted Tröger's bases

L Cerrada, J Cudero, J Elguero, C Pardo

Index: Cerrada, Luisa; Cudero, Jose; Elguero, Jose; Pardo, Carmen Journal of the Chemical Society, Chemical Communications, 1993 , # 23 p. 1713 - 1714

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Citation Number: 21

Abstract

Troger's bases 2'3 and 4 containing azole rings as substituents on the aromatic moiety have been synthesized for the first time. ... Troger's base 1 (2'8-dimethyl-5 ,Il-methano-5,6,11,12-tetra - hydrodibenzo[b,fl[ 1,5]diazocine), first synthesized by Troger in 1887,' is a concave chiral molecule. Prelog resolved it using chiral chromatography,* and more recently the resolution was carried out via diastereoisomeric salt formation .3 Troger's base analogues provide ...

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