Chelate-assisted, palladium-catalyzed efficient carbonylation of aryl chlorides

Y Ben-David, M Portnoy, D Milstein

Index: Ben-David, Yehoshua; Portnoy, Moshe; Milstein, David Journal of the American Chemical Society, 1989 , vol. 111, # 23 p. 8742 - 8744

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Citation Number: 188

Abstract

'Reaction conditions: A solution containing chlorobenzene (10 mmol), 1 (0.1 mmol), alcohol or water (1 mL), base (10 mmol), and solvent (3 mL) was heated at 150 OC for 20 h under 70 psi of CO. In amidation, 2 mL of amine was used. Similar results are obtained when P~(OAC)~+ 2dippp is used instead of 1. bIsolated yield. CGC yield. toward Pd-catalyzed carbonylation by stoichiometric utilization of their chromium tricarbonyl complexes was ...