Inorganic Chemistry 2010-02-01

Unprecedented marriage of a cationic pentanuclear cluster and a 2D polymeric anionic layer based on a flexible tripodal ligand and a Cu(II) ion.

Zheng-Bo Han, Guo-Xin Zhang, Ming-Hua Zeng, Da-Qiang Yuan, Qian-Rong Fang, Jian-Rong Li, Joan Ribas, Hong-Cai Zhou

Index: Inorg. Chem. 49(3) , 769-71, (2010)

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Abstract

The anionic CdI(2)-type topological net, [Cu(2)(tci)(2)](2-), and the pentanuclear copper cluster cation [Cu(5)(tci)(2)(OH)(2)(H(2)O)(8)](2+) [tci = tris(2-carboxyethyl)isocyanurate] form a complementary 3D supramolecular framework. Interestingly, there exist centrosymmetric cyclic (H(2)O)(18) clusters in the cavities.

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