Enantiospecific total synthesis of (-)-bengamide E.
Prashant K Metri, Raphael Schiess, Kavirayani R Prasad
Index: Chem. Asian J. 8(2) , 488-93, (2013)
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Abstract
Total synthesis of the polyhydroxy caprolactam amide natural product, bengamide E, is accomplished starting from tartaric acid. Key reactions in the synthesis include desymmetrization of the bis(dimethylamide) unit of tartaric acid, Zn(BH(4))(2)-mediated anti-selective reduction, and a Horner-Wadsworth-Emmons olefination.Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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