Study of the interaction polybutadiene/fillers using inverse gas chromatography.
Rachel Calvet, Sylvie Del Confetto, Henri Balard, Eric Brendlé, Jean-Baptiste Donnet
Index: J. Chromatogr. A. 1253 , 164-70, (2012)
Full Text: HTML
Abstract
In this study, the coupling of IGC-ID analysis and carbon blacks impregnation with increasing ratios of polymer allow us to highlight the affinity of the polymer to the solid surface. The variations of the dispersive component of the surface energy and of the nanomorphology index are monitored versus the degree of carbon black impregnation. A clear correlation between the decrease in the dispersive component of the surface energy and the increase in the nanomorphological index is observed. The PBu macromolecules shield progressively the slot shaped sites on the carbon blacks surface. IGC reveals clear differences in surface properties between CB of different grades.Copyright © 2012 Elsevier B.V. All rights reserved.
Related Compounds
Related Articles:
2011-09-15
[Talanta 85(3) , 1648-57, (2011)]
2012-08-01
[J. Am. Chem. Soc. 134(30) , 12685-92, (2012)]
Core-crosslinked compartmentalized cylinders.
2011-01-01
[Nanoscale 3(1) , 288-97, (2011)]
2012-08-30
[J. Hazard. Mater. 229-230 , 251-7, (2012)]
Adsorption of an azo dye in an aqueous solution using hydroxyl-terminated polybutadiene (HTPB).
2013-05-01
[Chemosphere 91(7) , 935-40, (2013)]