Photoinduced single electron transfer initiated heterolytic carbon-selenium bond dissociation. Sequential one-pot selenenylation and deselenenylation reaction
…, BBVS Sekhar, UT Bhalerao
Index: Pandey, Ganesh; Soma Sekhar; Bhalerao Journal of the American Chemical Society, 1990 , vol. 112, # 14 p. 5650 - 5651
Full Text: HTML
Citation Number: 33
Abstract
Recently we have reported in situ generation of electrophilic selenium (PhSe+) species via diphenyl diselenide radical cation (PhSeSePh)'+ formed by single electron transfer (SET) from PhSeSePh (1) to the excited singlet of 1, 4-dicyanonaphthalene (DCN, 2). l We report herein electron transfer (ET) from compounds possessing a carbonselenium bond to'DCN* leading to heterolytic C-Se bond dissociation via a radical cation intermediate with ...
Related Articles:
[Jones, Ray V.H.; Lindsell, W. Edward; Palmer, Daniel D.; Preston, Peter N.; Whitton, Alan J. Tetrahedron Letters, 2005 , vol. 46, # 50 p. 8695 - 8697]
New method for the synthesis of benzyl alkyl ethers mediated by FeSO4
[Joshi, Girdhar; Adimurthy, Subbarayappa Synthetic Communications, 2011 , vol. 41, # 5 p. 720 - 728]
[Boyer, Bernard; Keramane, El-Mehdi; Roque, Jean-Pierre; Pavia, Andre A. Tetrahedron Letters, 2000 , vol. 41, # 16 p. 2891 - 2894]
[Argouarch, Gilles; Grelaud, Guillaume; Roisnel, Thierry; Humphrey, Mark G.; Paul, Frederic Tetrahedron Letters, 2012 , vol. 53, # 37 p. 5015 - 5018]
Efficient method for the reductive cleavage of acetals and ketals with Zn (BH4) 2/Me3SiCl
[Kotsuki, Hiyoshizo; Ushio, Yasuyuki; Yoshimura, Naka; Ochi, Masamitsu Journal of Organic Chemistry, 1987 , vol. 52, # 12 p. 2594 - 2596]