Total Synthesis of TK??57??164A, Isariotin F, and Their Putative Progenitor Isariotin E

JY Cha, Y Huang, TRR Pettus

Index: Cha, Jacob Y.; Huang, Yaodong; Pettus, Thomas R. R. Angewandte Chemie - International Edition, 2009 , vol. 48, # 50 p. 9519 - 9521

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Citation Number: 20

Abstract

Cyclohexenone monoepoxides enjoy widespread attention because of their useful properties and structural complexity.[1] In a search for bioactive secondary metabolites of entomopathic fungi-afflicting insects, Bunyapaiboonsri et al. reported isolating two novel compounds, isariotin E (3) and F (2) along with the known bicycle TK-57-164A (1), a compound previously described as an agricultural bactericide.[2, 3] Isariotin F (2) ...