Organic Letters 2012-06-01

One-pot primary aminomethylation of aryl and heteroaryl halides with sodium phthalimidomethyltrifluoroborate.

Norio Murai, Masayuki Miyano, Masahiro Yonaga, Keigo Tanaka

Index: Org. Lett. 14(11) , 2818-21, (2012)

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Abstract

A one-pot primary aminomethylation of aryl halides, triflates, mesylates, and tosylates via Suzuki-Miyaura cross-coupling reactions with sodium phthalimidomethyltrifluoroborate followed by deamidation with ethylenediamine is reported.

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