Nickel Complexes of a Pincer Amidobis (amine) Ligand: Synthesis, Structure, and Activity in Stoichiometric and Catalytic C C Bond??Forming Reactions of Alkyl …

O Vechorkin, Z Csok, R Scopelliti…

Index: Vechorkin, Oleg; Csok, Zsolt; Scopelliti, Rosario; Hu, Xile Chemistry - A European Journal, 2009 , vol. 15, # 15 p. 3889 - 3899

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Citation Number: 73

Abstract

Abstract Get a grip! Ni II complexes of the new pincer amidobis (amine) ligand are described. The Ni chloride complex catalyzes Kumada–Corriu–Tamao coupling of unactivated alkyl halides with alkyl Grignard reagents, as well as double C–C coupling of CH 2 Cl 2 with alkyl Grignard reagents (see schemes).

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