Nickel??catalyzed Asymmetric Alkylation of Some Chiral and Achiral Allylic Alcohols. Preliminary communication
G Consiglio, F Morandini, O Piccolo
Index: Consiglio, Giambattista; Morandini,Franco; Piccolo, Oreste Helvetica Chimica Acta, 1980 , vol. 63, # 4 p. 987 - 989
Full Text: HTML
Citation Number: 19
Abstract
Abstract [(−)(R)-1, 2-bis (Diphenylphosphino)-1-phenylethane] nickel (II) chloride was found to catalyze the asymmetric alkylation of some chiral and achiral allylic alcohols with Grignard reagents, leading to the formation of optically active olefins. Enantiomer discrimination of the substrate takes place in the alkylation of chiral allylic alcohols.
Related Articles:
Selective hydrogenation by a novel palladium (II) complex
[Kerr, James M.; Suckling, Colin J. Tetrahedron Letters, 1988 , vol. 29, # 43 p. 5545 - 5548]
[Pater, Jerome P. G.; Jacobs, Pierre A.; Martens, Johan A. Journal of Catalysis, 1998 , vol. 179, # 2 p. 477 - 482]
[Zhao, Wei; Qian, Yanlong; Huang, Jiling; Duan, Jianjun Journal of Organometallic Chemistry, 2004 , vol. 689, # 16 p. 2614 - 2623]