On the preparation of acyl cyanides from aldehydes
H Härle, JC Jochims
Index: Haerle, Helmut; Jochims, Johannes C. Chemische Berichte, 1986 , vol. 119, # 4 p. 1400 - 1412
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Citation Number: 8
Abstract
The 0-silylated cyanohydrins 3 prepared from the aldehydes 1 with trimethylsilyl cyanide are oxidized photochemically or thermally with N-bromosuccinimide to afford the acyl cyanides 427 - n. Scope and limitations of the procedure are discussed. ... Zur Darstellung von Acylcyaniden aus Aldehyden Die aus den Aldehyden 1 mit Trimethylsilylcyanid dargestellten 0-silylierten Cyanhydrine 3 werden photochemisch oder thermisch mit N-Bromsuccinimid zu den Acylcyaniden 4a - ...
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