Application of hydrazinium monoformate as new hydrogen donor with Raney nickel: a facile reduction of nitro and nitrile moieties
S Gowda, DC Gowda
Index: Gowda, Shankare; Gowda, D.Channe Tetrahedron, 2002 , vol. 58, # 11 p. 2211 - 2213
Full Text: HTML
Citation Number: 90
Abstract
The nitro groups in aliphatic and aromatic nitrocompounds also containing reducible substituents such as ethene, acid, phenol, halogen, ester etc., are rapidly reduced at room temperature to corresponding amines by employing hydrazinium monoformate, a new hydrogen donor, in the presence of Raney nickel. It was observed that the nitrile function also undergoes reduction to methylamine (–CH2–NH2). Hydrazinium monoformate is a ...
Related Articles:
The preparation and base strengths of some amines
[Carothers; Bickford; Hurwitz Journal of the American Chemical Society, 1927 , vol. 49, p. 2908]
Synthesis of primary amines by one-pot reductive amination of aldehydes
[Ayedi, Mohamed Ali; Le Bigot, Yves; Ammar, Houcine; Abid, Souhir; Gharbi, Rachid El; Delmas, Michel Synthetic Communications, 2013 , vol. 43, # 16 p. 2127 - 2133]
The preparation and base strengths of some amines
[Carothers; Bickford; Hurwitz Journal of the American Chemical Society, 1927 , vol. 49, p. 2908]
Synthesis of primary amines by one-pot reductive amination of aldehydes
[Ayedi, Mohamed Ali; Le Bigot, Yves; Ammar, Houcine; Abid, Souhir; Gharbi, Rachid El; Delmas, Michel Synthetic Communications, 2013 , vol. 43, # 16 p. 2127 - 2133]
Stability of benzylic-type isothiocyanates in hydrodistillation-mimicking conditions
[De Nicola, Gina R.; Montaut, Sabine; Rollin, Patrick; Nyegue, Maximilienne; Menut, Chantal; Iori, Renato; Tatibouet, Arnaud Journal of Agricultural and Food Chemistry, 2013 , vol. 61, # 1 p. 137 - 142]