Spin Crossover-Coupled Electron Transfer of [M (tacn) 2] 3+/2+ Complexes (tacn= 1, 4, 7-Triazacyclononane; M= Cr, Mn, Fe, Co, Ni)

RL Lord, FA Schultz, MH Baik

Index: Jubb, Jayne; Larkworthy, Leslie F.; Oliver, Lee F.; Povey, David C.; Smith, Gallienus W. Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1991 , # 8 p. 2045 - 2050

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Citation Number: 28

Abstract

... Å), Fe (1.456 Å), Co (1.436 Å), Ni (1.417 Å), H (1.150 Å), C (1.900 Å ... free energy of reduction; E° = standard reduction potential; n = number of electrons; F = Faraday constant ... B3LYP* overestimated bond lengths by 0.05−0.10 Å consistent with previous findings.(18) Three metrics ...