Azide and fluoride exchange reactions of halodiazirines
…, DP Cox, DZ Denny, K Krogh-Jespersen
Index: Moss, Robert A.; Terpinski, Jacek; Cox, D. Phillip; Denneey, Dorothy Z.; Krogh-Jespersen, Karsten Journal of the American Chemical Society, 1985 , vol. 107, # 9 p. 2743 - 2748
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Citation Number: 71
Abstract
Abstract: Reactions of 3-aryl-3-bromodiazirines (11) with molten tetrabutylammonium fluoride at 25 OC provide 65-74% isolated yields of the novel corresponding 3-aryl-3- fluorodiazirines (12). Related reactions of 11 with tetrabutylammonium azide afford high yields of aryl nitriles. The latter reactions are believed to proceed through unstable intermediate 3-aryl-3-azidodiazirines (7). These reactions involve rate-determining ...
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