Substitution at a saturated carbon atom. XV. Ion-pair phenomena in selected allylic systems
RA Sneen, PS Kay
Index: Sneen,R.A.; Kay,P.S. Journal of the American Chemical Society, 1972 , vol. 94, p. 6983 - 6989
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Citation Number: 22
Abstract
Abstract: Kinetics and product distributions resulting from the competitive reactions of the primary y, y-dimethylallyl chloride and of the allylically isomeric tertiary a, a-dimethylallyl chloride with solvent and sodium azide in 80% aqueous acetone at 32.0” have been studied. Both substrates undergo a kinetically second-order reaction with sodium azide, the reaction with the tertiary substrate being either bimolecular attack at tertiary carbon or a ...
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