Stabilities of carbonium ions in solution. 12. Heats of formation of alkyl chlorides as an entree to heats of solvation of aliphatic carbonium ions

EM Arnett, NJ Pienta

Index: Arnett, Edward M.; Pienta, Norbert J. Journal of the American Chemical Society, 1980 , vol. 102, # 10 p. 3329 - 3334

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Citation Number: 43

Abstract

Abstract: Heats of formation (AHf) of tertiary alkyl chlorides may be calculated from measurements of the heats of hydrochlorination of appropriate olefins at-50 OC in CH2C12. Since many good values for heats of formation of the olefins have been published, the heats of hydrochlorination lead directly to Afff for the chlorides, for which few previous values are available. The new data, when combined with previously reported heats of ionization for ...