Suzuki-Miyaura cross-couplings of secondary allylic boronic esters.
Ben W Glasspoole, Kazem Ghozati, Jonathon W Moir, Cathleen M Crudden
Index: Chem. Commun. (Camb.) 9th ed., 48 , 1230-1232, (2012)
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Abstract
Palladium-catalyzed cross-coupling reactions of secondary allylic boronic esters with iodoarenes were demonstrated under the conditions previously described for the coupling of benzylic substrates. The regioselectivity of the process was largely dictated by the pattern of olefin substitution.
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