Products and reaction paths in the liquid phase oxidation of trans-1, 2-dichloroethene with oxygen
K Griesbaum, MP Hayes…
Index: Griesbaum, Karl; Hayes, Michael P.; Werli, Vera Canadian Journal of Chemistry, 1988 , vol. 66, p. 1366 - 1370
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Citation Number: 3
Abstract
Ultraviolet initiated liquid phase oxidation of neat trans-1, 2-dichloroethene (1 a) with oxygen at 30° C afforded ca. 45% of the combined Cl-products CO, CO2, and phosgene as well as nine oxygenated and nine non-oxygenated chlorinated organic products. Major oxygenated products were cis-and trans-2, 3-dichlorooxirane (6 a, b) and 1, 2, 2-trichloroethyl formate (13); minor products were eg, meso and rac bis (1, 2, 2-trichloroethyl) ether (11 c, d) and ...
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