Chlorine Dioxide as an Electron??Transfer Oxidant of Olefins. Preliminary Communication
C Rav??Acha, S Sarel
Index: Rav-Acha, Chaim; Choshen, Ehud; Sarel, Shalom Helvetica Chimica Acta, 1986 , vol. 69, p. 1728 - 1733
Full Text: HTML
Citation Number: 1
Abstract
Abstract The kinetics and product studies of oxidation of eight olefins 1-8 by ClO 2 in H 2 O in the pH range 3-7 are described. The reaction is faster as the pH decreases. At pH< 4, ClO 2 reacts equimolarly with olefins to yield isomeric mixtures of chlorohydrines and 1, 2- dioxygenated products, following the equation:
Related Articles:
[Mendes, Eduarda; Furtado, Tania; Neres, Joao; Iley, Jim; Jarvinen, Tomi; Rautio, Jarkko; Moreira, Rui Bioorganic and Medicinal Chemistry, 2002 , vol. 10, # 3 p. 809 - 816]
[Mendes, Eduarda; Furtado, Tania; Neres, Joao; Iley, Jim; Jarvinen, Tomi; Rautio, Jarkko; Moreira, Rui Bioorganic and Medicinal Chemistry, 2002 , vol. 10, # 3 p. 809 - 816]
Photochemical cleavage and release of carboxylic acids from α-keto amides
[Ma, Chicheng; Steinmetz, Mark G.; Kopatz, Erica J.; Rathore, Rajendra Journal of Organic Chemistry, 2005 , vol. 70, # 11 p. 4431 - 4442]
Photochemical cleavage and release of carboxylic acids from α-keto amides
[Ma, Chicheng; Steinmetz, Mark G.; Kopatz, Erica J.; Rathore, Rajendra Journal of Organic Chemistry, 2005 , vol. 70, # 11 p. 4431 - 4442]
Photochemical cleavage and release of carboxylic acids from α-keto amides
[Ma, Chicheng; Steinmetz, Mark G.; Kopatz, Erica J.; Rathore, Rajendra Journal of Organic Chemistry, 2005 , vol. 70, # 11 p. 4431 - 4442]