Rh nanoparticle catalyzed hydroaminomethylation of 1-octene in thermoregulated ionic liquid and organic biphasic system.
Yicheng Xu, Yanhua Wang, Kaoxue Li, Mingming Niu, Yan Zeng, Jingyang Jiang, Zilin Jin
Index: J. Nanosci. Nanotechnol. 13(7) , 5048-52, (2013)
Full Text: HTML
Abstract
Thermoregulated ionic liquid and organic biphasic system composed of ionic liquid [CH3(OCH2 CH2)22N+Et3][CH3SO3-] (abbreviated as IL(PEG1000)) containing IL(PEG1000)-stabilized Rh nanoparticles and organic solvent, which allows for not only highly efficient homogeneous reaction but also an easy biphasic separation, was applied to the hydroaminomethylation of 1-octene for the first time. Under the optimized conditions, the conversion of 1-octene and the amine selectivity were 100% and 90%, respectively. After reaction, the Rh nanoparticle catalyst could be easily separated by simple decantation and reused for four times without evident loss in activity.
Related Compounds
Related Articles:
Toxic impact of bromide and iodide on drinking water disinfected with chlorine or chloramines.
2014-10-21
[Environ. Sci. Technol. 48(20) , 12362-9, (2014)]
2015-06-15
[Inorg. Chem. 54 , 5827-38, (2015)]
2013-03-18
[Angew. Chem. Int. Ed. Engl. 52(12) , 3411-6, (2013)]
Lead exposure causes thyroid abnormalities in diabetic rats.
2015-01-01
[Int. J. Clin. Exp. Med. 8 , 7160-7, (2015)]
2015-04-01
[Anal. Bioanal. Chem 407(11) , 3093-102, (2015)]