Synthesis and Anti-HBV Activity of Thiouracils Linked via S and N-1 to the 5-Position of Methyl β-D-Ribofuranoside

AAH Abdel-Rahman, AES Abdel-Megied…

Index: Abdel-Rahman, Adel A.-H.; Abdel-Megied, Ahmed E.-S.; Goda, Adel E.-S.; Zeid, Ibrahim F.; El Ashry, El Sayed H. Nucleosides, Nucleotides and Nucleic Acids, 2003 , vol. 22, # 11 p. 2027 - 2038

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Citation Number: 11

Abstract

Abstract Reverse nucleoside derivatives of 2-(methylsulfanyl) uracils 6a-d were prepared by treating of the sodium salt of 2-(methylsulfanyl) uracils (5a-d) with methyl 2, 3-O- isopropylidene-5-Op-toluenesulfonyl-β-D-ribofuranoside (2). The alkylation of 2-thiouracils 4a-d with methyl 5-deoxy-5-iodo-2, 3-O-isopropylidene-D-ribofuranoside (3) afforded the corresponding S-ribofuranoside derivatives 8a-d. Deisopropylidenation of 6a-d and 8a-d ...

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