Journal of Organometallic Chemistry

Organometallic chemistry and catalysis on gold metal surfaces

RJ Angelici

Index: Angelici, Robert J. Journal of Organometallic Chemistry, 2008 , vol. 693, # 5 p. 847 - 856

Full Text: HTML

Citation Number: 49

Abstract

As in transition metal complexes, CN–R ligands adsorbed on powdered gold undergo attack by amines to give putative diaminocarbene groups on the gold surface. This reaction forms the basis for the discovery of a gold metal-catalyzed reaction of CN–R, primary amines (R′ NH2) and O2 to give carbodiimides (R′–NCN–R). An analogous reaction of CO, RNH2, and O2 gives isocyanates (R–NCO), which react with additional amine to give urea (RNH) ...

Related Articles:

An efficient, scaleable procedure for the conversion of esters to isoxazoles

[Bunnelle; Singam; Narayanan; Bradshaw; Liou Synthesis, 1997 , # 4 p. 439 - 442]

Competing radical, carbanion, and carbene pathways in the reactions of hindered primary alkyl halides with lithium dialkylamides

[Ashby, E. C.; Park, B.; Patil, G. S.; Gadru, K.; Gurumurthy, R. Journal of Organic Chemistry, 1993 , vol. 58, p. 424 - 437]

PHOTOCATALYTIC FORMATION OF SCHIFF BASES FROM PRIMARY AMINES BY PLATINIZED-TiO 2 SUSPENSION IN ACETONITRILE

[Ohtani, Bunsho; Osaki, Haruyoshi; Nishimoto, Sei-Ichi; Kagiya, Tsutomu Chemistry Letters, 1985 , p. 1075 - 1078]

Synthesis, Structure and Theoretical Studies of the Hydrido Inverse Crown [K2Mg2 (NiPr2) 4 (μ??H) 2·(toluene) 2]: a Rare Example of a Molecular Magnesium Hydride …

[Andrikopoulos, Prokopis C.; Armstrong, David R.; Kennedy, Alan R.; Mulvey, Robert E.; O'Hara, Charles T.; Rowlings, Rene B. European Journal of Inorganic Chemistry, 2003 , # 18 p. 3354 - 3362]

PHOTOCATALYTIC FORMATION OF SCHIFF BASES FROM PRIMARY AMINES BY PLATINIZED-TiO 2 SUSPENSION IN ACETONITRILE

[Ohtani, Bunsho; Osaki, Haruyoshi; Nishimoto, Sei-Ichi; Kagiya, Tsutomu Chemistry Letters, 1985 , p. 1075 - 1078]

More Articles...