Conversions of 2-Phenyl-1, 3, 2-dioxaphospholane Under the Action of Hydrogen Chloride
SN Lazarev, ZA Bredikhina, AA Bredikhin
Index: Lazarev; Bredikhina; Bredikhin Russian Journal of General Chemistry, 2003 , vol. 73, # 6 p. 928 - 932
Full Text: HTML
Citation Number: 1
Abstract
Abstract The reaction of 2-phenyl-1, 3, 2-dioxaphospholane with HCl gives a mixture of phenylphosphinic acid, bis (2-chloroethyl) phenylphosphonate, and phenylphosphine; therewith, intermediate oligomeric phosphonites, hydrophosphoryl compounds, and phosphoranes were detected. Thermal treatment of the reaction mixture results in formation of ethylene phenylphosphonate and (2-chloroethyl) phenylphosphinate.
Related Articles:
Hydrolysis of spirobicyclic oxyphosphoranes. Associative and dissociative reactions
[McClelland, Robert A.; Patel, Geeta; Cirinna, Corrado Journal of the American Chemical Society, 1981 , vol. 103, # 21 p. 6432 - 6436]
Hydrolysis of spirobicyclic oxyphosphoranes. Associative and dissociative reactions
[McClelland, Robert A.; Patel, Geeta; Cirinna, Corrado Journal of the American Chemical Society, 1981 , vol. 103, # 21 p. 6432 - 6436]
Part I: The Development of the Catalytic Wittig Reaction
[O'Brien, Christopher J.; Nixon, Zachary S.; Holohan, Andrew J.; Kunkel, Stephen R.; Tellez, Jennifer L.; Doonan, Bryan J.; Coyle, Emma E.; Lavigne, Florie; Kang, Lauren J.; Przeworski, Katherine C. Chemistry - A European Journal, 2013 , vol. 19, # 45 p. 15281 - 15289]
Photolytic rearrangement of phosphorus azide: evidence for a transient metaphosphonimidate.
[Bertrand, Guy; Majoral, Jean-Pierre; Baceiredo, Antoine Tetrahedron Letters, 1980 , vol. 21, p. 5015 - 5018]
Photolytic rearrangement of phosphorus azide: evidence for a transient metaphosphonimidate.
[Bertrand, Guy; Majoral, Jean-Pierre; Baceiredo, Antoine Tetrahedron Letters, 1980 , vol. 21, p. 5015 - 5018]