Silver Acetate Mediated Acetoxylations of Alkyl Halides
R Nolla-Saltiel, UA Carrillo-Arcos, S Porcel
Index: Nolla-Saltiel, Roberto; Carrillo-Arcos, Ulises Alonso; Porcel, Susana Synthesis (Germany), 2014 , vol. 46, # 2 p. 165 - 169
Full Text: HTML
Citation Number: 1
Abstract
Abstract Silver acetate promotes the acetoxylation of alkyl halides under neutral reaction conditions. The reaction is applicable to primary and activated secondary alkyl halides, and 2, 2-dibromoacetophenones for preparing the corresponding acetates in good yields. The presence of ester, amide, nitrile, hydroxy, and OTBDMS functions on the substrate is tolerated.
Related Articles:
[Nelson, Michael E.; Priestley, Nigel D. Journal of the American Chemical Society, 2002 , vol. 124, # 12 p. 2894 - 2902]
The esterification of carboxylic acid with alcohol over hydrous zirconium oxide.
[Takahashi, Kyoko; Shibagaki, Makoto; Matsushita, Hajime Bulletin of the Chemical Society of Japan, 1989 , vol. 62, # 7 p. 2353 - 2361]
Microwave??Assisted NiCl2 Promoted Acylation of Alcohols
[Constantinou-Kokotou, Violetta; Peristeraki, Anna Synthetic Communications, 2004 , vol. 34, # 22 p. 4227 - 4232]
N-Acyl 1, 5-diazabicyclo [4.3. 0] non-5-ene (DBN) tetraphenylborate salts as O-acylating agents
[Taylor, James E.; Williams, Jonathan M.J.; Bull, Steven D. Tetrahedron Letters, 2012 , vol. 53, # 32 p. 4074 - 4076]
[Tetrahedron Letters, , vol. 54, # 14 p. 1813 - 1816]