Preparation of graphene-ZrO2 nanocomposites by heat treatment and photocatalytic degradation of organic dyes.

Bum Hwi Cho, Weon Bae Ko

Index: J. Nanosci. Nanotechnol. 13(11) , 7625-30, (2013)

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Abstract

ZrO2 nanoparticles were synthesized by combining a solution containing zinconyl chloride in distilled water with a NH4OH solution under microwave irradiation. Graphene and ZrO2 nanocomposites were synthesized in an electric furnace at 700 degrees C for 2 hours. The heated graphene-ZrO2 nanocomposites were characterized by X-ray diffraction, scanning electron microscopy and transmission electron microscopy. In addition, UV-vis spectrophotometry was used to evaluate the heated graphene-ZrO2 nanocomposites as a catalyst in the photocatalytic degradation of organic dyes. The photocatalytic effect of the heated graphene-ZrO2 nanocomposites was compared with that of unheated graphene nanoparticles, heated graphene nanoparticles, and unheated graphene-ZrO2 nanocomposites in organic dyes (methylene blue, methyl orange, and rhodamine B) under ultraviolet light at 254 nm.