The synthesis and application of novel nitrating and nitrosating agents

…, H Zarrinmayeh, A Khalafi??Nezhad

Index: Hakimelahi, Gholam H.; Sharghi, Hashem; Zarrinmayeh, Hamide; Khalafi-Nezhad, Ali Helvetica Chimica Acta, 1984 , vol. 67, p. 906 - 915

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Citation Number: 18

Abstract

Abstract Alcohols and phenols are efficiently nitrated with thionyl chloride nitrate or thionyl nitrate, even in the presence of an aromatic moiety. While thionyl chloride nitrate is suitable for nitration of primary OH-groups in carbohydrates, thionyl nitrate is reactive enough to react with secondary OH-groups as well. These reagents permit the highly selective nitration of the 5′-, 2′ 5′-and 3′, 5′-OH-groups of ribonucleosides to produce either mono-or ...