Tetrahedron

Sensitized photo-oxygenation of acyclic conjugated dienes

M Matsumoto, S Dobashi, K Kuroda, K Kondo

Index: Matsumoto, Masakatsu; Dobashi, Satoshi; Kuroda, Keiko; Kondo, Kiyosi Tetrahedron, 1985 , vol. 41, # 11 p. 2147 - 2154

Full Text: HTML

Citation Number: 53

Abstract

Sensitized photo-oxygenation of a wide variety of acyclic 1, 3-dienes was investigated. The 1, 4-cycloaddition of singlet oxygen to acyclic conjugated dienes was closely related to the thermal Diels-Alder reaction in stereospecificity, and steric and electronic effects of substituents. Reactivity order of singlet oxygen toward conjugated dienes and isolated C—C double bonds was exhibited as follows: trisubstituted mono-olefins> 2-substituted 1, 3- ...

Related Articles:

Homogeneous oxidation reactions of propanediols at low temperatures

[ChemSusChem, , vol. 3, # 9 p. 1063 - 1070]

Rubidium-and caesium-doped silicotungstic acid catalysts supported on alumina for the catalytic dehydration of glycerol to acrolein

[Journal of Catalysis, , vol. 286, p. 206 - 213]

Oxetene: synthesis and energetics of electrocyclic ring opening

[Journal of the American Chemical Society, , vol. 102, # 16 p. 5429 - 5430]

Synthesis of meso??and (±)??2, 2′??bis (carboxymethoxy) oxydiacetic acid via cis??and trans??2, 5??(diallyloxy)??2, 5??dihydrofuran: Model compounds for the calcium …

[Nieuwenhuizen, M.S.; Kieboom, A.P.G.; Bekkum, H. van Recueil: Journal of the Royal Netherlands Chemical Society, 1982 , vol. 101, # 10 p. 339 - 342]

Propriétés catalytiques de bronzes orthorhombiques de molybdène ou tungstène au bismuth ou à l'antimoine, de formulation (MIII2O) M'10O30 (M

[Bulletin de la Societe Chimique de France, , # 6 p. 745 - 752]

More Articles...