A Product Analytical Study of the Thermal and Photolytic Decomposition of Some Arenediazonium Salts in Solution.

PSJ Canning, H Maskill, K McCrudden…

Index: Canning, Peter S. J.; Maskill, Howard; McCrudden, Katharine; Sexton, Brian Bulletin of the Chemical Society of Japan, 2002 , vol. 75, # 4 p. 789 - 800

Full Text: HTML

Citation Number: 33

Abstract

Products of thermal and photochemical reactions of eleven arenediazonium tetrafluoroborates in various solvents have been analyzed. All compounds in most solvents undergo unimolecular heterolysis to give singlet aryl cations which are captured by solvent. This mechanism is dominant for arenediazonium ions without electron-withdrawing substituents in all solvents, and the only reaction observed in water. Additionally, ...

Related Articles:

Mechanistic Studies on Fluorobenzene Synthesis from 1, 1-Difluorocyclohexane via Pd-Catalyzed Dehydrofluoro-Dehydrogenation

[Tojo, Masahiro; Fukuoka, Shinsuke; Tsukube, Hiroshi Bulletin of the Chemical Society of Japan, 2011 , vol. 84, # 3 p. 333 - 340]

A series of NiM (M= Ru, Rh, and Pd) bimetallic catalysts for effective lignin hydrogenolysis in water

[Chatterjee, Maya; Ishizaka, Takayuki; Suzuki, Akira; Kawanami, Hajime Chemical Communications, 2013 , vol. 49, # 40 p. 4567 - 4569]

Electroreductive dehalogenation of fluorobenzenes

[Kariv-Miller, Essie; Vajtner, Zlatko Journal of Organic Chemistry, 1985 , vol. 50, # 9 p. 1394 - 1399]

Aryl fluorides from the reaction of boron trifluoride with aryl-lead (IV) triacetates, which may be generated in situ from aryltrimethylsilanes, triarylboroxines, and arenes

[Meio, Giuseppe V. De; Pinhey, John T. Journal of the Chemical Society, Chemical Communications, 1990 , # 15 p. 1065 - 1066]

Mechanistic Studies on Fluorobenzene Synthesis from 1, 1-Difluorocyclohexane via Pd-Catalyzed Dehydrofluoro-Dehydrogenation

[Tojo, Masahiro; Fukuoka, Shinsuke; Tsukube, Hiroshi Bulletin of the Chemical Society of Japan, 2011 , vol. 84, # 3 p. 333 - 340]

More Articles...