Novel phosphonium chloride-catalyzed dehydrohalogenative Si-C coupling reaction of alkyl halides with trichlorosilane

…, SH Kang, JS Han, BR Yoo, IN Jung

Index: Yeon Seok Cho; Kang; Joon Soo Han; Bok Ryul Yoo; Il Nam Jung Journal of the American Chemical Society, 2001 , vol. 123, # 23 p. 5584 - 5585

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Citation Number: 17

Abstract

Si-C bond forming reactions such as the direct synthesis, 1 hydrosilylation, 2 and general organometallic reactions3 are important methods for the preparation of various organosilicon compounds. Another established Si-C bond forming reaction is the coupling of activated organic chlorides with trichlorosilane (1a) commonly known as the Benkeser reaction. 4 Although this reaction generally proceeds in good yields, the reaction ...