Gas-Phase Ion-Molecular Reactions of Free Ethylsilylium Ions with Ethylene

…, TA Kochina, EN Sinotova, IS Ignat'ev

Index: Shchukin; Kochina; Sinotova; Ignat'ev Russian Journal of General Chemistry, 2001 , vol. 71, # 2 p. 206 - 209

Full Text: HTML

Citation Number: 3

Abstract

Abstract Gas-phase reaction of ethylsilylium ions with ethylene was studied by the radiochemical method. The reaction occurs via excited adduct C 4 H 11 Si+ which structurally is a complex of ethylsilylium cation with ethylene. The lifetime of this complex is long enough for the isotope exchange between tritium atoms of the cation and a proton of ethylene, as well as the isomerization of ethylsilylium cation to dimethylsilylium to occur. ...

Related Articles:

Formation of organosilicon compounds 115: the applicability as precursors for β-SiC of carbosilanes resulting from the gas phase pyrolysis of methylsilanes

[Toegel; Antony; Bill; Scheer, Petra; Eichhoefer; Fritz Journal of Organometallic Chemistry, 1996 , vol. 521, # 1-2 p. 125 - 131]

From carbon dioxide to methane: Homogeneous reduction of carbon dioxide with hydrosilanes catalyzed by zirconium-borane complexes

[Matsuo, Tsukasa; Kawaguchi, Hiroyuki Journal of the American Chemical Society, 2006 , vol. 128, # 38 p. 12362 - 12363]

The vibrational spectra of germane and silane derivatives—XII. A reassignment of the dimethylhalosilanes

[Clark, Allan J. F.; Drake, John E.; Hemmings, T. Raymond; Shen, Quang Spectrochimica Acta, Part A: Molecular and Biomolecular Spectroscopy, 1983 , vol. 39, # 2 p. 127 - 136]

Unusual Cleavage of the≡ SiOSi≡ Group by Organosilicon Hydrides: A New Route to α, ω-Dihydrooligopermethylsiloxanes

[Voronkov; Basenko; Gebel'; Chuvashev Doklady Chemistry, 2003 , vol. 393, # 4-6 p. 289 - 291]

Mechanism of the gas-phase thermolysis of monomethylsilane

[Neudorfl, P. S.; Lown, E. M.; Safarik, I.; Jodhan, A.; Strausz, O. P. Journal of the American Chemical Society, 1987 , vol. 109, # 19 p. 5780 - 5789]

More Articles...