Zinc-catalyzed nucleophilic substitution reaction of chlorosilanes with organomagnesium reagents
K Murakami, H Yorimitsu, K Oshima
Index: Murakami, Kei; Yorimitsu, Hideki; Oshima, Koichiro Journal of Organic Chemistry, 2009 , vol. 74, # 3 p. 1415 - 1417
Full Text: HTML
Citation Number: 39
Abstract
Zinc-catalyzed nucleophilic substitution reactions of chlorosilanes with organomagnesium reagents afford various tetraorganosilanes under mild reaction conditions. The reactions can be performed on large scale and allow efficient preparation of functionalized tetraorganosilanes.
Related Articles:
Rhodium (II)-Catalyzed Stereoselective Synthesis of Allylsilanes
[Guptill, David M.; Cohen, Carolyn M.; Davies, Huw M. L. Organic Letters, 2013 , vol. 15, # 24 p. 6120 - 6123]
Kinetics of the reactions of allylsilanes, allylgermanes, and allylstannanes with carbenium ions
[Hagen, Gisela; Mayr, Herbert Journal of the American Chemical Society, 1991 , vol. 113, # 13 p. 4954 - 4961]
Copper-catalyzed arylation of chlorosilanes with Grignard reagents
[Morita, Eiji; Murakami, Kei; Iwasaki, Masayuki; Hirano, Koji; Yorimitsu, Hideki; Oshima, Koichiro Bulletin of the Chemical Society of Japan, 2009 , vol. 82, # 8 p. 1012 - 1014]
[Muchowski, Joseph M.; Naef, Reto; Maddox, Michael L. Tetrahedron Letters, 1985 , vol. 26, # 44 p. 5375 - 5378]