Perfluorocarbon fluids as solvent replacements

RD Chambers, AR Edwards

Index: Chambers, Richard D.; Edwards, Andrew R. Journal of the Chemical Society - Perkin Transactions 1, 1997 , # 24 p. 3623 - 3627

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Citation Number: 23

Abstract

Perfluoroperhydrophenanthrene 1 may be used as a 'bulking agent'to minimise the problem of solvent recovery in halogen exchange ('Halex') reactions for the preparation of octafluorocyclopentene 8, and chlorofluoro-pyridine,-pyrimidine and-benzene derivatives. New 'one-pot'procedures for the syntheses of hexaflu