Photo??oxidative dealkylation of α??alkylbenzyl methyl ethers induced by titanium dioxide in acetonitrile
…, TD Giacco, C Rol, GV Sebastiani
Index: Del Giacco, Tiziana; Rol, Cesare; Sebastiani, Giovanni V. Journal of Physical Organic Chemistry, 2003 , vol. 16, # 2 p. 127 - 132
Full Text: HTML
Citation Number: 10
Abstract
Abstract TiO 2-sensitised photo-oxidation of α-alkylbenzyl methyl ethers in deaerated CH 3 CN gives the expected corresponding ketone, whereas in an aerated medium a dealkylation compound (methyl benzoate) is obtained as the principal product, with respect to the ketone, or the exclusive product (when the alkyl group is tert-butyl). The product analysis and distribution, together with a qualitative estimate of the relative reactivity, suggest that the ...
Related Articles:
[Jiang, Jianwen; Wang, Pingping; Cai, Mingzhong Journal of Chemical Research, 2014 , vol. 38, # 4 p. 218 - 222]
[Bleloch, Andrew; Johnson, Brian F. G.; Ley, Steven V.; Price, Adam J.; Shephard, Douglas S.; Thomas, Andrew W. Chemical Communications, 1999 , # 18 p. 1907 - 1908]
A practical non-cryogenic process for the selective functionalization of bromoaryls
[Gallou, Fabrice; Haenggi, Ruedi; Hirt, Hans; Marterer, Wolfgang; Schaefer, Frank; Seeger-Weibel, Manuela Tetrahedron Letters, 2008 , vol. 49, # 34 p. 5024 - 5027]
[Miyamoto, Kazunori; Tada, Norihiro; Ochiai, Masahito Journal of the American Chemical Society, 2007 , vol. 129, # 10 p. 2772 - 2773]
[Miyamoto, Kazunori; Tada, Norihiro; Ochiai, Masahito Journal of the American Chemical Society, 2007 , vol. 129, # 10 p. 2772 - 2773]