Catalysis Communications

The reductive amination of cyclohexanone with 1, 6-diaminohexane over alumina B modified Cu–Cr–La/γ-Al 2 O 3

M Sun, X Du, X Kong, L Lu, Y Li, L Chen

Index: Sun, Meng; Du, Xiaobao; Kong, Xiangjin; Lu, Liang; Li, Yang; Chen, Ligong Catalysis Communications, 2012 , vol. 20, p. 58 - 62

Full Text: HTML

Citation Number: 4

Abstract

The reductive amination of cyclohexanone with 1, 6-diaminohexane over alumina B modified Cu–Cr–La/γ-Al2O3 was investigated. The experimental results indicated that the doped alumina B remarkably increased the selectivity of N, N′-dicyclohexyl-1, 6- diaminohexane. The catalysts were studied by BET, XRD, TEM and NH3-TPD, the introduction of alumina B to Cu–Cr–La/γ-Al2O3 reduced the strong acid capacity of the ...

Related Articles:

Organozinc reagents in synthesis: the facile generation of 2-(trialkylsilyl) prop-2-enylzinc from 2-bromo-1-trimethylsilylprop-2-ene

[Eshelby, James J.; Parsons, Philip J.; Crowley, Patrick J. Journal of the Chemical Society - Perkin Transactions 1, 1996 , # 2 p. 191 - 199]

Organometallic compounds of Group III. Part 43. Alkylenation with geminal dialuminoalkane reagents: the synthesis of olefins from ketones

[Piotrowski, Andrzej M.; Malpass, Dennis B.; Boleslawski, Marek P.; Eisch, John J. Journal of Organic Chemistry, 1988 , vol. 53, # 12 p. 2829 - 2835]

Interannular diastereoselectivity in the hydroboration of functionalized 1-cyclohexylcyclohexenes

[Bell, Thomas W.; Vargas, J. Ramon; Crispino, Gerard A. Journal of Organic Chemistry, 1989 , vol. 54, # 8 p. 1978 - 1987]

Selective hydrogenation of nitrocyclohexane to cyclohexanone oxime with H 2 on decorated Pt nanoparticles

[Serna, Pedro; Lopez-Haro; Calvino; Corma, Avelino Journal of Catalysis, 2009 , vol. 263, # 2 p. 328 - 334]

Selective hydrogenation of nitrocyclohexane to cyclohexanone oxime with H 2 on decorated Pt nanoparticles

[Serna, Pedro; Lopez-Haro; Calvino; Corma, Avelino Journal of Catalysis, 2009 , vol. 263, # 2 p. 328 - 334]

More Articles...