The Journal of organic chemistry

Triethylborane-initiated room temperature radical addition of hypophosphites to olefins: synthesis of monosubstituted phosphinic acids and esters

S Deprele, JL Montchamp

Index: Devedjiev, I.; Borisov, G. Phosphorus, Sulfur and Silicon and the Related Elements, 1990 , vol. 53, # 1-4 p. 37 - 42

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Citation Number: 104

Abstract

... Volume: Page: ... We now report the convenient, mild, and selective reaction of sodium hypophosphite and related species with alkenes, initiated at ... 12 Yet, to our knowledge, they were never employed to generate phosphorus-centered radicals for P−C bond ...

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