Regioselectivity of Intermolecular Pauson–Khand Reaction of Aliphatic Alkynes: Experimental and Theoretical Study of the Effect of Alkyne Polarization

…, X Verdaguer, A Riera, J Helaja

Index: Liu, Yan-Yun; Yang, Xu-Heng; Huang, Xiao-Cheng; Wei, Wen-Ting; Song, Ren-Jie; Li, Jin-Heng Journal of Organic Chemistry, 2013 , vol. 78, # 20 p. 10421 - 10426

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Citation Number: 3

Abstract

... The Journal of Organic ... Laboratory of Organic Chemistry, Department of ... 3 equiv, c = 5 equiv, d = 10 equiv; (2) solvent amount (e,f) e = 6 mL of toluene, f = 1.5 mL of toluene; (3) reaction temperature (g,h) g = 90 °C, h = 50 °C; (4) heat source (i) MW (70 °C); (5) alkene (j) NBN; (6 ...