Reactivity of carbamoyl radicals. A new, general, convenient free-radical synthesis of isocyanates from monoamides of oxalic acid

F Minisci, F Fontana, F Coppa…

Index: Journal of Organic Chemistry, , vol. 60, # 17 p. 5430 - 5433

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Citation Number: 12

Abstract

... (1) Richter, R.; Ulrich, H. The Chemistry ofCyanates and their ... must be very soluble in the organic solvent: this way, the oxidation of the monoamide of oxalic acid takes place in the aqueous phase while the isocyanate is very rapidly extracted by the organic solvent, thus ... J. Org. ...

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