A new rearrangement of alkoxybenzyl anions
…, TJ Siahaan, K Suvannachut
Index: Bates, Robert B.; Siahaan, Teruna J.; Suvannachut, Kessara Journal of Organic Chemistry, 1990 , vol. 55, # 4 p. 1328 - 1334
Full Text: HTML
Citation Number: 15
Abstract
Alkyl groups migrate from oxygen to carbon in alkyl aryl ethers which have been metalated in benzylic positions. 2, 6-Dimethylanisole provides a variety of 2, 6-dialkylphenols and their ethers in 45-80% yields. Rearrangement products are obtained in 10-30% yields from other dimethylanisoles and from methylanisoles. The reactions appear to proceed, like Wittig rearrangements, by homolytic cleavage of the alkyl-oxygen bond followed by ...
Related Articles:
[Schmid,M. et al. Helvetica Chimica Acta, 1971 , vol. 54, p. 937 - 951]
[Schmid,M. et al. Helvetica Chimica Acta, 1971 , vol. 54, p. 937 - 951]
[Schmid,M. et al. Helvetica Chimica Acta, 1971 , vol. 54, p. 937 - 951]
The Pyrolysis of Allyl 2, 4, 6-Trialkylphenyl Ethers
[Hurd; Yarnall Journal of the American Chemical Society, 1937 , vol. 59, p. 1686,1688]
The Pyrolysis of Allyl 2, 4, 6-Trialkylphenyl Ethers
[Hurd; Yarnall Journal of the American Chemical Society, 1937 , vol. 59, p. 1686,1688]