Chloroarylation and thiocyanatoarylation of itaconic acid

VS Baranovskii, BM Petrushka, AY Fesak…

Index: Baranovskii; Petrushka; Fesak; Grishchuk Russian Journal of General Chemistry, 2013 , vol. 83, # 2 p. 325 - 328 Zh. Obshch. Khim., 2013 , vol. 83, # 2 p. 271 - 274,4

Full Text: HTML

Citation Number: 1

Abstract

Abstract Under conditions of Meerwein reaction and anionarylation the aryldiazonium salts and itaconic acid form 2-chloro (thiocyanato)-2-benzylbutanedioic acids as the chloro-and thiocyianatoarylation products. The reaction is not accompanied by the decarboxylation process and other transformations affecting the carboxy groups of itaconic acid.

Related Articles:

A new efficient synthesis of isothiocyanates from amines using di-tert-butyl dicarbonate

[Munch, Henrik; Hansen, Jon S.; Pittelkow, Michael; Christensen, Jorn B.; Boas, Ulrik Tetrahedron Letters, 2008 , vol. 49, # 19 p. 3117 - 3119]

Synthesis and Pesticidal Properties of Thio and Seleno Analogs of Some Common Urea Herbicides

[Zakrzewski, Jerzy; Krawczyk, Maria Phosphorus, Sulfur and Silicon and the Related Elements, 2009 , vol. 184, # 7 p. 1880 - 1903]

A convenient synthesis of isothiocyanates from nitrile oxides

[Kim, Jae Nyoung; Ryu, Eung K. Tetrahedron Letters, 1993 , vol. 34, # 51 p. 8283 - 8284]

A general synthesis of isothiocyanates from dithiocarbamates using Claycop

[Mesheram, Harashadas M.; Dale, Srinivas; Yadav Tetrahedron Letters, 1997 , vol. 38, # 50 p. 8743 - 8744]

Desulfurization mediated by hypervalent iodine (III): A novel strategy for the construction of heterocycles

[Ghosh, Harisadhan; Yella, Ramesh; Nath, Jayashree; Patel, Bhisma K. European Journal of Organic Chemistry, 2008 , # 36 p. 6189 - 6196]

More Articles...