Ultrasound-accelerated selective oxidation of primary aromatic amines to azoxy derivatives with trans-3, 5-dihydroperoxy-3, 5-dimethyl-1, 2-dioxolane catalyzed by …

D Azarifar, SM Khatami, Z Najminejad

Index: Azarifar, Davood; Khatami, Seyed-Mola; Najminejad, Zohreh Journal of the Iranian Chemical Society, 2014 , vol. 11, # 2 p. 587 - 592

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Abstract

Abstract Preyssler-type heteropolyacid supported on TiO 2 nanoparticles has been explored as an efficient catalyst in selective oxidation of primary aromatic amines to azoxy derivatives using trans-3, 5-dihydroperoxy-3, 5-dimethyl-1, 2-dioxolane as oxidant. The reactions proceeded smoothly under mild and green ultrasound-accelerated conditions to afford the products in high yields. The catalyst recovered from the reaction mixture exhibits long-term ...

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