Palladium??Catalyzed Arylation of Cyclopentadienes
…, JI Inoh, S Pivsa??Art, T Satoh, M Nomura
Index: Dyker, Gerald; Heiermann, Joerg; Miura, Masahiro; Inoh, Jun-Ichi; Pivsa-Art, Sommai; Satoh, Tetsuya; Nomura, Masakatsu Chemistry - A European Journal, 2000 , vol. 6, # 18 p. 3426 - 3433
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Citation Number: 48
Abstract
Abstract Cyclopentadiene and metallocenes, typically zirconocene dichloride, are suitable substrates for multiple arylations with aryl bromides in palladium-catalyzed reactions. Thus, various aryl bromides bearing either an electron-donating or an electron-withdrawing substituent can react with these substrates to afford the corresponding 1, 2, 3, 4, 5-pentaaryl- 1, 3-cyclopentadienes in a single preparative step. Derivatives of cyclopentadiene, ...
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