Chloro(5,10,15,20-tetraphenylporphyrinato)manganese(III) with 4/m symmetry.
B Cheng, W R Scheidt
Index: Acta Crystallogr. C 52 ( Pt 2) , 361-3, (1996)
Full Text: HTML
Abstract
The crystal structure of [Mn(TPP)Cl] in space group I4/m (where TPP is C44H28N4) has been determined. The unit cell contains two full molecules, with one eighth of a molecule unique. An out-of-plane model for the Mn atom was applied and all non-H atoms were refined anisotropically. The Mn--N distance is 2.002 (3) A, the axial Mn--Cl distance is 2.297 (15) A and the out-of-plane displacement of the Mn atom is 0.16 A. The possibility of a reverse-doming porphyrin core conformation is mentioned briefly.
Related Compounds
Related Articles:
2006-04-01
[Bioorg. Med. Chem. Lett. 16(7) , 2026-30, (2006)]
2002-04-01
[Spectrochim. Acta. A. Mol. Biomol. Spectrosc. 58(6) , 1113-27, (2002)]
Detection of meat-borne trimethylamine based on nanoporous colorimetric sensor arrays.
2016-04-15
[Food Chem. 197 , 930-6, (2015)]
A novel histidine assay using tetraphenylporphyrin manganese (III) chloride as a molecular recognition probe by resonance light scattering technique. Chen, Zhanguang, et al.
[Anal. Chim. Acta 570 , 109-115, (2006)]
M.J. Cha et al.
[Anal. Chim. Acta 315 , 311, (1995)]