Formal Homo??Nazarov and Other Cyclization Reactions of Activated Cyclopropanes
…, T Saget, F Benfatti, S Almeida, J Waser
Index: De Simone, Filippo; Saget, Tanguy; Benfatti, Fides; Almeida, Sofia; Waser, Jerome Chemistry - A European Journal, 2011 , vol. 17, # 51 p. 14527 - 14538
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Citation Number: 47
Abstract
Abstract The Nazarov cyclization of divinyl ketones gives access to cyclopentenones. Replacing one of the vinyl groups by a cyclopropane leads to a formal homo-Nazarov process for the synthesis of cyclohexenones. In contrast to the Nazarov reaction, the cyclization of vinyl-cyclopropyl ketones is a stepwise process, often requiring harsh conditions. Herein, we describe two different approaches for further polarization of the ...
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