A simple method for the determination of organochlorine pollutants and the enantiomers in oil seeds based on matrix solid-phase dispersion.

Jing Zhan, Jindong Li, Donghui Liu, Chang Liu, Genggeng Yang, Zhiqiang Zhou, Peng Wang

Index: Food Chem. 194 , 319-24, (2015)

Full Text: HTML

Abstract

A simple, rapid and effective method was developed based on matrix solid-phase dispersion (MSPD) for the determination of organochlorine pollutants including sixteen organochlorine pesticides (OCPs) and seven polychlorinated biphenyls (PCBs) in oil seeds (peanuts and soybeans). Among the organochlorine pollutants selected, α-HCH, heptachlor, o,p'-DDT, o,p'-DDD, trans-chlordane and cis-chlordane were chiral and their enantiomers were determined by GC-ECD with a chiral column. The MSPD procedure was optimized focusing on the type and amount of dispersion sorbent, co-column sorbent and eluting solvent. Under the optimized condition, good recoveries were obtained in the range of 68.9-103.3% with relative standard deviations (RSD) values below 16.1% in all cases. LODs and LOQs were in range of 0.1-2.0ngg(-1) and 0.4-6.7ngg(-1) respectively. In summary, the method set up was qualified to be used for the determination of the pollutants and the enantiomers in oil seeds.Copyright © 2015 Elsevier Ltd. All rights reserved.