New attempt for CO 2 utilization: One-pot catalytic syntheses of methyl, ethyl and n-butyl carbamates

J Li, X Qi, L Wang, Y He, Y Deng

Index: Li, Jian; Qi, Xiujuan; Wang, Liguo; He, Yude; Deng, Youquan Catalysis Communications, 2011 , vol. 12, # 13 p. 1224 - 1227

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Citation Number: 9

Abstract

Abstract The direct production of methyl, ethyl and n-butyl carbamates (MC, EC and BC) from NH 3, CO 2 and alcohols could efficiently be catalyzed by V 2 O 5, and ca. 11–25% yields with 98% selectivity for alkyl carbamates could be obtained. The catalyst could be recycled six times without obvious decrease in catalytic activity. XRD and XPS analysis showed that in-situ produced (NH 4) 2 V 3 O 8 was the catalytically active species.